Research Article
Open Access
Influence of Mn2+ doping on the optical properties of ZnSxO1-xquantum dots
G. Janita Christobel1* and C.K. Mahadevan2
1Physics Research Centre, S. T. Hindu College, Nagercoil-629002, Tamil Nadu, India
2Center for Scientific and Applied Research, PSN College of Engineering and Technology, Melathediyoor, Tirunelveli-627152, Tamil Nadu, India
2Center for Scientific and Applied Research, PSN College of Engineering and Technology, Melathediyoor, Tirunelveli-627152, Tamil Nadu, India
G. Janita Christobel et al /Int.J. TechnoChem Res. 2016,2(3),pp 217-223.
Abstract
The physical properties of two semiconductor quantum dots like ZnO and ZnS are found to
get modified significantly when they are mixed with each other or doped with a transition metal element.
With an aim of discovering new useful quantum dots, in the present study, we have prepared Mn2+ doped
ZnSxO1-x nanocomposite quantum dots (x = 0.0, 0.2, 0.4, 0.5, 0.6, 0.8 and 1.0) by a simple solvothermal
method using a domestic microwave oven. Powder X-ray diffraction, scanning electron microscopic and
energy dispersive X-ray absorption spectroscopic analyses were carried out to characterise the prepared
quantum dots chemically and structurally. UV-Vis-NIR absorption, photoluminescence (PL) and
photoconductivity measurements have been carried out to understand the influence of Mn2+ doping on
the optical properties of ZnSxO1-x quantum dots. Results obtained indicate significant changes in the
optical properties like absorption edge wavelength, PL yield and photoconductivity. All the nanocrystals
(quantum dots) prepared in the present study are found to have their absorption edge wavelengths within
the UV region, exhibit five prominent peaks (observed at around 400, 440,480, 490 and 530 nm) in the
PL spectra and possess positive photoconductivity.
get modified significantly when they are mixed with each other or doped with a transition metal element.
With an aim of discovering new useful quantum dots, in the present study, we have prepared Mn2+ doped
ZnSxO1-x nanocomposite quantum dots (x = 0.0, 0.2, 0.4, 0.5, 0.6, 0.8 and 1.0) by a simple solvothermal
method using a domestic microwave oven. Powder X-ray diffraction, scanning electron microscopic and
energy dispersive X-ray absorption spectroscopic analyses were carried out to characterise the prepared
quantum dots chemically and structurally. UV-Vis-NIR absorption, photoluminescence (PL) and
photoconductivity measurements have been carried out to understand the influence of Mn2+ doping on
the optical properties of ZnSxO1-x quantum dots. Results obtained indicate significant changes in the
optical properties like absorption edge wavelength, PL yield and photoconductivity. All the nanocrystals
(quantum dots) prepared in the present study are found to have their absorption edge wavelengths within
the UV region, exhibit five prominent peaks (observed at around 400, 440,480, 490 and 530 nm) in the
PL spectra and possess positive photoconductivity.
Keywords
Quantum dots, Doped ZnSxO1-x nanocrystals, Solvothermal method, Optical properties.
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